Photoelectron angular distributions from the ionization of xenon Rydberg states by midinfrared radiation

Accepted

Angle-resolved photoelectron spectra, resulting from the strong field ionization of atoms or molecules, carry a rich amount of information on ionization pathways, electron dynamics and the target structure. We have investigated angle-resolved photoelectron spectra arising from the nonresonant ionization of xenon Rydberg atoms in the multi-photon regime, using intense mid-infrared radiation from a Free Electron Laser. The experimental data reveal a rich oscillatory structure in the low-order above threshold ionization (ATI) region. By performing quantum mechanical and semiclassical calculations, the observed oscillations could be well reproduced and explained by both a multi-photon absorption picture as by a model invoking electron wave-packet interferences. Furthermore, we demonstrate that the shape and orientation of the initial Rydberg state leaves its own fingerprint on the final angular distribution.