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Phys. Rev. A 81, 032503 (2010) [8 pages]

Lifetimes and branching ratios of excited states in La-, Os-, Lu-, Lr-, and Pr-

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Steven M. O’Malley and Donald R. Beck
Physics Department, Michigan Technological University, Houghton, Michigan 49931, USA

Received 21 December 2009; published 5 March 2010

Relativistic configuration-interaction calculations have been performed for all possible E1, M1, and E2 transitions between bound anion states of La- and Os-. We pay particular attention to E1 transitions in each case that may be of use in laser cooling of these anions. Although the La- transition energy is approximately one-third of the Os- transition, our results indicate that the Einstein A coefficient is nearly two orders of magnitude larger, which would lead to more efficient laser cooling. We have also explored long-lived opposite-parity excited states in Lu- and Lr- which are restricted to M2 decay by selection rules. Finally, in Pr-, we find sufficient mixing between a weakly bound excited 4f25d26s2 state with a nearby 4f36s26p resonance to result in a lifetime similar to that of the other excited anion states, despite the fact that the dominant configurations of these M1 and E2 transitions differ by two electrons.

© 2010 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.81.032503
DOI:
10.1103/PhysRevA.81.032503
PACS:
31.15.am, 32.70.Cs, 31.15.vj, 32.10.Hq