Phys. Rev. A 79, 056501 (2009) [2 pages]Comment on “Ground state of octahedral platinum hexafluoride”Received 10 June 2008; published 6 May 2009 It is shown that the principal results of a recent work by Alvarez-Thon et al. Phys. Rev. A 77 034502 (2008)] are in conflict with earlier work of the present authors [ JETP Lett. 73 35 (2001)] and also with a well known result concerning magnetic properties, NMR, and Jahn-Teller effect in the systems possessing even number of d electrons. This can be attributed to the fact that Alvarez-Thon et al. did not account for the influence of 19F and 195Pt nuclear magnetic moments and vibronic interactions on the wave function of PtF6 molecules. © 2009 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevA.79.056501
DOI:
10.1103/PhysRevA.79.056501
PACS:
31.15.aj, 31.30.jc
See AlsoOriginal Article: Luis Alvarez-Thon, J. David, Ramiro Arratia-Pérez, and Konrad Seppelt, Ground state of octahedral platinum hexafluoride, Phys. Rev. A 77, 034502 (2008). |
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