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Phys. Rev. A 77, 030501(R) (2008) [4 pages]

Ortho-para transition in molecular hydrogen

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Krzysztof Pachucki*
Institute of Theoretical Physics, University of Warsaw, Hoża 69, 00-681 Warsaw, Poland

Jacek Komasa
Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

Received 22 December 2007; published 14 March 2008

The radiative ortho-para transition in molecular hydrogen is studied. This highly forbidden transition is very sensitive to relativistic and subtle nonadiabatic effects. Our result for the transition rate in the ground vibrational level Γ(J=1→J=0)=6.20(62)×10−14 yr−1 is significantly lower in comparison to all the previous approximate calculations. Experimental detection of such a weak line by observation of, for example, cold interstellar molecular hydrogen is at present unlikely.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.77.030501
DOI:
10.1103/PhysRevA.77.030501
PACS:
31.15.ac, 31.30.J-, 33.70.Ca, 95.30.Ky

*krp@fuw.edu.pl

komasa@man.poznan.pl