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Phys. Rev. A 75, 042509 (2007) [14 pages]

Dispersion coefficients of the excited states of lithium atoms

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J.-Y. Zhang* and J. Mitroy
Faculty of Technology, Charles Darwin University, Darwin NT 0909, Australia

M. W. J. Bromley
Department of Physics and Computational Sciences Research Center, San Diego State University, San Diego, California 92182, USA

Received 22 December 2006; revised 30 January 2007; published 19 April 2007

The dispersion coefficients of a number of the low-lying states of Li are determined for the homonuclear case. The Li wave functions and energies were computed in a frozen core Hamiltonian with a semiempirical polarization potential. Besides computing the dispersion coefficients, the scalar and tensor polarizabilities and oscillator strengths are computed and generally seen to be in good agreement with other accurate calculations.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.75.042509
DOI:
10.1103/PhysRevA.75.042509
PACS:
31.25.Jf, 34.20.Cf, 31.15.Pf, 32.10.Dk

*Electronic address: jun-yi.zhang@cdu.edu.au

Electronic address: jxm107@rsphysse.anu.edu.au

Electronic address: mbromley@physics.sdsu.edu