Phys. Rev. A 66, 066501 (2002) [3 pages]Comment on “Kinetic energy as a density functional”Received 3 April 2002; published 20 December 2002 In a recent paper, Nesbet [Phys. Rev. A 65, 010502(R) (2001)] has proposed dropping “the widespread but unjustified assumption that the existence of a ground-state density functional for the kinetic energy, Ts[ρ], of an N-electron system implies the existence of a density-functional derivative, δTs[ρ]/δρ(r), equivalent to a local potential function,” because, according to his arguments, this derivative “has the mathematical character of a linear operator that acts on orbital wave functions.” Our Comment demonstrates that the statement called by Nesbet an “unjustified assumption” happens, in fact, to be a rigorously proven theorem. Therefore, his previous conclusions stemming from his different view of this derivative, which undermined the foundations of density-functional theory, can be discounted. © 2002 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevA.66.066501
DOI:
10.1103/PhysRevA.66.066501
PACS:
31.15.Ew, 31.10.+z, 71.10.-w
See AlsoOriginal Article: R. K. Nesbet, Kinetic energy as a density functional, Phys. Rev. A 65, 010502 (2001). |
