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Phys. Rev. A 66, 066501 (2002) [3 pages]

Comment on “Kinetic energy as a density functional”

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A. Holas
Institute of Physical Chemistry of the Polish Academy of Sciences, 44/52 Kasprzaka, 01-224 Warsaw, Poland

N. H. March
University of Oxford, Oxford, England
Department of Physics (RUCA), University of Antwerp, B-2020 Antwerp, Belgium

Received 3 April 2002; published 20 December 2002

In a recent paper, Nesbet [Phys. Rev. A 65, 010502(R) (2001)] has proposed dropping “the widespread but unjustified assumption that the existence of a ground-state density functional for the kinetic energy, Ts[ρ], of an N-electron system implies the existence of a density-functional derivative, δTs[ρ]/δρ(r), equivalent to a local potential function,” because, according to his arguments, this derivative “has the mathematical character of a linear operator that acts on orbital wave functions.” Our Comment demonstrates that the statement called by Nesbet an “unjustified assumption” happens, in fact, to be a rigorously proven theorem. Therefore, his previous conclusions stemming from his different view of this derivative, which undermined the foundations of density-functional theory, can be discounted.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.66.066501
DOI:
10.1103/PhysRevA.66.066501
PACS:
31.15.Ew, 31.10.+z, 71.10.-w

See Also

Original Article: R. K. Nesbet, Kinetic energy as a density functional, Phys. Rev. A 65, 010502 (2001).