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Phys. Rev. A 65, 033403 (2002) [8 pages]

Strong-field ionization dynamics of a model H2 molecule

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Manfred Lein1, Thomas Kreibich2, E. K. U. Gross3, and Volker Engel4
1Blackett Laboratory, Imperial College of Science, Technology and Medicine, London SW7 2BW, United Kingdom
2Institut für Theoretische Physik, Am Hubland, D-97074 Würzburg, Germany
3Institut für Theoretische Physik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany
4Institut für Physikalische Chemie, Am Hubland, D-97074 Würzburg, Germany

Received 28 August 2001; published 1 February 2002

We investigate the dynamics of a one-dimensional H2 model molecule in strong laser fields by numerical integration of the time-dependent Schrödinger equation without the use of the Born–Oppenheimer approximation. Ionization typically occurs at internuclear separations close to the ground-state equilibrium distance. This is contrary to the case of H2+, which ionizes at larger internuclear distances where charge-resonance-enhanced ionization is possible. Similar to the case of atoms, we find considerable nonsequential double ionization.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.65.033403
DOI:
10.1103/PhysRevA.65.033403
PACS:
33.80.Rv, 31.70.Hq