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Phys. Rev. A 55, 4273–4284 (1997)

X-ray fluorescence and Auger-electron coincidence spectroscopyof vacancy cascades in atomic argon

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U. Arp1, T. LeBrun2, S. H. Southworth2, M. A. MacDonald3, and M. Jung2
11Electron and Optical Physics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899
22Physics Division, Argonne National Laboratory, Argonne, Illinois 60439
33EPSRC Daresbury Laboratory, Warrington WA4 4AD, United Kingdom

Received 20 February 1997; published in the issue dated June 1997

Argon L2,3-M2,3M2,3 Auger-electron spectra were measured in coincidence with Kα fluorescent x rays in studies of K-shell vacancy decays at several photon energies above the K threshold and on the 1s→4p resonance. The complex spectra recorded by conventional electron spectroscopy are greatly simplified when recorded in coincidence with fluorescent x rays, allowing a more detailed analysis of the vacancy cascade process. The resulting coincidence spectra are compared with Hartree-Fock calculations, which include shake-up transitions in the resonant case. Small energy shifts of the coincident electron spectra are attributed to postcollision interaction with 1s photoelectrons.

© 1997 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.55.4273
DOI:
10.1103/PhysRevA.55.4273
PACS:
32.80.Hd, 32.50.+d