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Phys. Rev. A 32, 2725–2738 (1985)

Multichannel quantum-defect theory and an equivalent N-level system

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W. E. Cooke and C. L. Cromer
Physics Department, University of Southern California, Los Angeles, California 90089-0484

Received 11 March 1985; published in the issue dated November 1985

A derivation and geometrical interpretation of multichannel quantum-defect theory (MQDT) is presented. An alternative set of MQDT parameters is suggested which separates into two independent groups, one representing the quantum defect of a Rydberg series in the absence of channel coupling and the other representing the channel coupling itself. An equivalent N-level system is developed so that the MQDT boundary conditions are replaced by a simple energy restriction on the N-level system, resulting in easier solutions of the equations. The equations are solved and spectra are presented for the simple two-channel case and for the three-channel case, where channel interactions lead to interferences in the spectra.

© 1985 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevA.32.2725
DOI:
10.1103/PhysRevA.32.2725
PACS:
31.10.+z, 31.60.+b, 32.70.Jz, 32.80.Dz